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Chemistry Help?

Combustion analysis of 63.8 mg of a C, H and O containing compound produced 145.0 mg of CO2 and 59.38 mg of H2O. What is the empirical formula for the compound?

A) C3H7O B) C5H2O C) C3H6O D) C6HO3 E) CHO

1 Answer

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  • 1 decade ago
    Favourite answer

    ( ) is the % mass of an element

    Carbon: 145 mg x (12.01 g / 44.01 g) = 39.6 mg

    Hydrogen: 59.38 mg x (2 x 1.008 g / 18.02 g) = 6.64 mg

    why did we calculate these elements? because all carbon and hydrogen end up in these two compounds.

    Mass of oxygen = 63.8 mg - 39.6 mg - 6.64 mg = 17.6 mg

    With all masses for 3 elements you can calculate the empirical formula:

    C: 39.6 mg * 1 mmol / 12.01 mg = 3.25 mmol

    H: 6.64 mg * 1 mmol / 1.008 mg = 6.59 mmol

    O: 17.6 mg * 1 mmol / 16.00 mg = 1.10 mmol

    divide all three by the smallest number, 1.10

    C:H:O = 2.95:5.99:1

    The choice is C. C3 : H6 : O1

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